Propeller-shaped chain and 2D grid coordination polymers with the host molecule cyclotriveratrylene and (CB9H5Br5)-

被引：17

作者：

Ahmad, R ^{[1
]}

Hardie, MJ ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 11期

关键词：

D O I：

10.1039/b405031b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The host molecule cyclotriveratrylene (CTV) forms coordination polymers with the Group 1 metals K 1 and Rb+ and with the carbaborane (CB9H5Br5)- as the counter-anion. [K(CTV)(2)](CB9H5Br5)(CF3CH2OH)(2) has a chain structure with an unusual propeller-shaped cross-section, while [Rb(CTV)(CB9H5Br5)(CH3CN)] has a two-dimensional grid structure of distorted hexagonal topology and is one of the few examples of a rubidium acetonitrile complex.

引用

页码：1315 / 1319

页数：5

共 50 条

[21] A 3,12-connected vertice sharing adamantoid hydrogen bonded network featuring tetrameric clusters of cyclotriveratrylene [J].

Hardie, MJ ;

Raston, CL ;

Salinas, A .

CHEMICAL COMMUNICATIONS, 2001, (18) :1850-1851

[22]

Hardie MJ, 2000, ANGEW CHEM INT EDIT, V39, P3835, DOI 10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO

[23]

2-Q

[24]

Hardie MJ, 2000, CHEM-EUR J, V6, P3293, DOI 10.1002/1521-3765(20000901)6:17<3293::AID-CHEM3293>3.3.CO

[25]

2-W

[26] Effect of anions on the framework formation of novel AgI coordination polymers with angular bridging ligands [J].

Huang, Z ;

Du, M ;

Song, HB ;

Bu, XH .

CRYSTAL GROWTH & DESIGN, 2004, 4 (01) :71-78

[27] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

[28] A critical account on π-π stacking in metal complexes with aromatic nitrogen-containing ligands [J].

Janiak, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3885-3896

[29] Engineering coordination polymers towards applications [J].

Janiak, C .

DALTON TRANSACTIONS, 2003, (14) :2781-2804

[30] The formation of a single-bonded (C70-)2 dimer in a new ionic multicomponent complex of cyclotriveratrylene:: (Cs+)2(C70-)2•CTV•(DMF)7(C6H6)0.75 [J].

Konarev, DV ;

Khasanov, SS ;

Vorontsov, II ;

Saito, G ;

Antipin, MY ;

Otsuka, A ;

Lyubovskaya, RN .

CHEMICAL COMMUNICATIONS, 2002, (21) :2548-2549

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