A molybdenum crown cluster forms discrete inorganic-organic nanocomposites with metalloporphyrins

被引：66

作者：

Tsuda, A ^{[1
]}

Hirahara, E ^{[1
]}

Kim, YS ^{[1
]}

Tanaka, H ^{[1
]}

Kawai, T ^{[1
]}

Aida, T ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 46期

关键词：

inorganic/organic nanocomposites; polyoxomolybdates; porphyrinoids; scanning probe microscopy; supramolecular chemistry;

D O I：

10.1002/anie.200460990

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Filled doughnuts: Molybdenum crown cluster MC accommodates up to three molecules of aminophenyl-substituted metalloporphyrins through hydrogen-bonding interactions, to form discrete inorganic-organic nanocomposite materials (see picture; blue polyhedra = MC, space-filling model = metalloporphyrin). Ultrahigh-vacuum scanning tunneling microscopy, in conjunction with scanning tunneling spectroscopy, at 80 K confirms the formation of the inclusion complex. (Figure presented).

引用

页码：6327 / 6331

页数：5

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