Diels-Alder reaction of anthracene and N-ethylmaleimide on the carbosilane dendrimer

被引：23

作者：

Kim, C ^{[1
]}

Kim, H

Park, K

机构：

[1] Dong A Univ, Dept Chem, Pusan 604714, South Korea

[2] Chungnam Natl Univ, Dept Pharm, Taejon 305764, South Korea

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 667卷 / 1-2期

关键词：

dendrimer; carbosilane; siloxane; Diels-Alder; maleimide;

D O I：

10.1016/S0022-328X(02)02148-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dendrimers with bicyclo-groups on the periphery were synthesized by the Diels-Alder (DA) reaction between anthracene derivatives, which have 24, 48 and 96 end-groups, and N-ethylmaleimide under the mild condition. The structural information of the DA product on dendritic periphery was obtained from hyperfine structural view of H-1-NMR spectroscopy. The purity of the products was determined by size exclusion chromatography. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：96 / 102

页数：7

共 37 条

[1] Archut A, 1998, CHEM-EUR J, V4, P699, DOI 10.1002/(SICI)1521-3765(19980416)4:4<699::AID-CHEM699>3.0.CO
[2] 2-9
[3] Dendritic catalysts and dendrimers in catalysis
Astruc, D
Chardac, F
[J]. CHEMICAL REVIEWS, 2001, 101 (09) : 2991 - 3023
[4] Diastereomeric control of photoinduced Diels-Alder reactions of 1-anthracen-9-yl-ethanol by hydrogen-bonding effects
Atherton, JCC
Jones, S
[J]. TETRAHEDRON LETTERS, 2001, 42 (46) : 8239 - 8241
[5] About dendrimers: Structure, physical properties, and applications
Bosman, AW
Janssen, HM
Meijer, EW
[J]. CHEMICAL REVIEWS, 1999, 99 (07) : 1665 - 1688
[6] Total synthesis of (+)-hatomarubigin B
Caygill, GB
Larsen, DS
Brooker, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (22) : 7427 - 7431
[7] Detecting the adsorption of dye molecules in homogeneous polypropylene imine) dendrimer monolayers by surface plasmon resonance sensor
Chen, SF
Yu, QM
Li, LY
Boozer, CL
Homola, J
Yee, SS
Jiang, SY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (13) : 3395 - 3401
[8] COEDOVA A, 2001, J AM CHEM SOC, V123, P8248
[9] Dendrimer-encapsulated metal nanoparticles: Synthesis, characterization, and applications to catalysis
Crooks, RM
Zhao, MQ
Sun, L
Chechik, V
Yeung, LK
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) : 181 - 190
[10] Noncovalently functionalized dendrimers as recyclable catalysts
de Groot, D
de Waal, BFM
Reek, JNH
Schenning, APHJ
Kramer, PCJ
Meijer, EW
van Leeuwen, PWNM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) : 8453 - 8458

← 1 2 3 4 →