Diels-Alder reaction of anthracene and N-ethylmaleimide on the carbosilane dendrimer

被引:23
作者
Kim, C [1 ]
Kim, H
Park, K
机构
[1] Dong A Univ, Dept Chem, Pusan 604714, South Korea
[2] Chungnam Natl Univ, Dept Pharm, Taejon 305764, South Korea
关键词
dendrimer; carbosilane; siloxane; Diels-Alder; maleimide;
D O I
10.1016/S0022-328X(02)02148-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dendrimers with bicyclo-groups on the periphery were synthesized by the Diels-Alder (DA) reaction between anthracene derivatives, which have 24, 48 and 96 end-groups, and N-ethylmaleimide under the mild condition. The structural information of the DA product on dendritic periphery was obtained from hyperfine structural view of H-1-NMR spectroscopy. The purity of the products was determined by size exclusion chromatography. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:96 / 102
页数:7
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