Diels-Alder reaction of anthracene and N-ethylmaleimide on the carbosilane dendrimer

被引：23

作者：

Kim, C ^{[1
]}

Kim, H

Park, K

机构：

[1] Dong A Univ, Dept Chem, Pusan 604714, South Korea

[2] Chungnam Natl Univ, Dept Pharm, Taejon 305764, South Korea

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 667卷 / 1-2期

关键词：

dendrimer; carbosilane; siloxane; Diels-Alder; maleimide;

D O I：

10.1016/S0022-328X(02)02148-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dendrimers with bicyclo-groups on the periphery were synthesized by the Diels-Alder (DA) reaction between anthracene derivatives, which have 24, 48 and 96 end-groups, and N-ethylmaleimide under the mild condition. The structural information of the DA product on dendritic periphery was obtained from hyperfine structural view of H-1-NMR spectroscopy. The purity of the products was determined by size exclusion chromatography. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：96 / 102

页数：7

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