Measurements for the kinetic parameters of electrocatalytic oxidation of ethanol at the nickel nanowire electrode

被引：7

作者：

Kong, JL ^{[1
]}

Xue, KH ^{[1
]}

Shao, Y ^{[1
]}

He, CJ ^{[1
]}

Chen, QL ^{[1
]}

机构：

[1] Nanjing Normal Univ, Dept Chem, Nanjing 210097, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 2002年 / 18卷 / 03期

关键词：

nickel nanowire; electrocatalysis; ethanol; cyclic voltammetry; forced convection hydrodynamic method;

D O I：

10.3866/PKU.WHXB20020316

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrocatalytic-oxidation of ethanol at the nickel nanowire electrode was investigated by cyclic voltammetry and the forced convection hydrodynamic method. The kinetic parameters of the reaction were measured and it was found that the rate constants of the electron transfer processes on the nanowire electrode were much higher than those reported in the literatures, but the rate constant of the step following the electron transfer process was comparable to the reported values.

引用

页码：268 / 271

页数：4

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