Symmetry and shape issues in nanostructure growth

被引:38
作者
Halder, Aditi [1 ]
Kundu, Paromita [1 ]
Viswanath, B. [1 ]
Ravishankar, N. [1 ]
机构
[1] Indian Inst Sci, Mat Res Ctr, Bangalore 560012, Karnataka, India
关键词
ORIENTED ATTACHMENT; NANOPARTICLE SHAPE; NANOCRYSTAL GROWTH; COLLOIDAL SOLUTION; GOLD NANOPRISMS; CRYSTAL HABITS; SILVER; NANORODS; NANOWIRES; MECHANISM;
D O I
10.1039/b925996a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Symmetry plays a key role in dictating the equilibrium morphology of crystals. However, several growth morphologies that deviate from the point group symmetry are routinely observed under several different growth conditions. In this article, we present a summary of symmetry-breaking mechanisms that are operative for crystals grown from the vapour phase as well as those formed as a result of wet chemical synthesis. This understanding is crucial for rationalizing the variety of morphologies observed during nanocrystal synthesis and also provides a rational framework for the synthesis of anisotropic nanostructures.
引用
收藏
页码:4763 / 4772
页数:10
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