Direct patterning of conductive water-soluble polyaniline for thin-film organic electronics

被引:66
作者
Lee, KS
Blanchet, GB
Gao, F
Loo, YL [1 ]
机构
[1] Univ Texas, Dept Chem Engn, Austin, TX 78712 USA
[2] DuPont Co Inc, Cent Res, Wilmington, DE 19880 USA
[3] Univ Texas, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.1862345
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report a simple and low-cost technique for directly patterning conductive water-soluble polyaniline. This technique exploits the hydrophilic nature of polyaniline that was synthesized on a polymer acid template. To create conductive features, aqueous polyaniline solutions are directly spun cast onto substrates previously patterned with hydrophilic and hydrophobic regions. Polyaniline selectively adsorbs in the hydrophilic regions thereby resulting in features as small as 5 mum with an average conductivity of 0.3 S/cm over large areas. Polyaniline contacts for thin-film transistors were fabricated; such devices show on characteristics that are quantitatively similar to those of reference devices with gold electrodes. (C) 2005 American Institute of Physics.
引用
收藏
页码:1 / 3
页数:3
相关论文
共 19 条
[1]  
ANGELOPOULOS M, 1994, Patent No. 5370825
[2]   Contact resistance in organic thin film transistors [J].
Blanchet, GB ;
Fincher, CR ;
Lefenfeld, M ;
Rogers, JA .
APPLIED PHYSICS LETTERS, 2004, 84 (02) :296-298
[3]   Large area, high resolution, dry printing of conducting polymers for organic electronics [J].
Blanchet, GB ;
Loo, YL ;
Rogers, JA ;
Gao, F ;
Fincher, CR .
APPLIED PHYSICS LETTERS, 2003, 82 (03) :463-465
[4]   Gate voltage dependent mobility of oligothiophene field-effect transistors [J].
Horowitz, G ;
Hajlaoui, R ;
Fichou, D ;
El Kassmi, A .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (06) :3202-3206
[5]   Selective deposition of conducting polymers on hydroxyl-terminated surfaces with printed monolayers of alkylsiloxanes as templates [J].
Huang, ZY ;
Wang, PC ;
MacDiarmid, AG ;
Xia, YN ;
Whitesides, G .
LANGMUIR, 1997, 13 (24) :6480-6484
[6]   Structure and stability of patterned self-assembled films of octadecyltrichlorosilane formed by contact printing [J].
Jeon, NL ;
Finnie, K ;
Branshaw, K ;
Nuzzo, RG .
LANGMUIR, 1997, 13 (13) :3382-3391
[7]   Pentacene thin film transistors on inorganic dielectrics:: Morphology, structural properties, and electronic transport [J].
Knipp, D ;
Street, RA ;
Völkel, A ;
Ho, J .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (01) :347-355
[8]   Control of carrier density by self-assembled monolayers in organic field-effect transistors [J].
Kobayashi, S ;
Nishikawa, T ;
Takenobu, T ;
Mori, S ;
Shimoda, T ;
Mitani, T ;
Shimotani, H ;
Yoshimoto, N ;
Ogawa, S ;
Iwasa, Y .
NATURE MATERIALS, 2004, 3 (05) :317-322
[9]   Optical investigation of intra and interchain charge dynamics in conducting polymers [J].
Lee, K ;
Heeger, AJ .
SYNTHETIC METALS, 2002, 128 (03) :279-282
[10]   Patterned conductive polyaniline on Si(100) surface via self-assembly and graft polymerization [J].
Li, ZF ;
Ruckenstein, E .
MACROMOLECULES, 2002, 35 (25) :9506-9512