Synthesis, characterization and third-order nonlinear optical properties of ruthenium(II) complexes containing 2-(4-nitrophenyl)imidazo[4,5-f] [1,10] phenanthroline

被引：16

作者：

Chao, H ^{[1
]}

Yuan, YX ^{[1
]}

Ji, LN ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Dept Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2004年 / 29卷 / 07期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1007/s11243-004-9169-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel Ru-II complexes [Ru(phen)(2)(PNOPH)](2+) and [Ru(dmp)(2)(PNOPH)](2+) (phen = 1,10-phenanthroline, dmp = 2,9-dimethyl-1,10-phenanthroline, PNOPH = 2-(4-nitrophenyl)imidazo-[4,5-f][1,10]phenanthroline) and their deprotoned complexes were synthesized and characterized by ES-MS, H-1- n.m.r, u.v.-vis. and electrochemistry. The crystal structure of the deprotonated complex [Ru(dmp)(2)(PNOP)][ClO4].CH3CN was determined by means of X-ray single crystal diffraction. Nonlinear optical properties of the RuII complexes were investigated by Z-scan techniques in DMF solution, and all of them exhibited both NLO absorption and self-defocusing effect. The corresponding effective NLO susceptibilities \chi(3)\ of the complexes are 2.39 x 10(-12)-5.80 x 10(-12) esu.

引用

页码：774 / 779

页数：6

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[21] APPLICATION OF THE ENERGY-GAP LAW TO EXCITED-STATE DECAY OF OSMIUM(II) POLYPYRIDINE COMPLEXES - CALCULATION OF RELATIVE NONRADIATIVE DECAY-RATES FROM EMISSION SPECTRAL PROFILES [J].