Friedel-crafts alkylation of α-methylnaphthalene in the presence of ionic liquids

被引：20

作者：

Zhao, ZK ^{[1
]}

Qiao, WH ^{[1
]}

Li, ZS ^{[1
]}

Wang, GR ^{[1
]}

Cheng, LB ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 222卷 / 1-2期

关键词：

ionic liquids; alkylation; alpha-methylnaphthalene; long-chain alkenes; HY and USY;

D O I：

10.1016/j.molcata.2004.08.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkylations of alpha-methylnaphthalene with long-chain alkenes (mixed C11-12 olefins) in the presence of room temperature ionic liquids and zeolite catalysts have been investigated. The influences of various parameters, such as type and dosage of catalyst, molar ratio of alpha-methylnaphthalene to alkenes, reaction temperature, and reaction time were studied. The EtxNH4-xCl-AlCl3 (x = 1-3, 0.67-0.75 molar fraction of aluminum trichloride) ionic liquids, compared with HY, USY zeolite and the other ethylamine-containing ionic liquids, were found to catalyze the reaction with high conversion of long-chain olefins and good selectivity for monoalkylated methyl naphthalene. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：207 / 212

页数：6

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