Trimethylsilyl derivatives of aliphatic nitro compounds in α,β-C,C-cross-coupling

被引：7

作者：

Dilman, AD ^{[1
]}

Lyapkalo, IM ^{[1
]}

Ioffe, SL ^{[1
]}

Strelenko, YA ^{[1
]}

Tartakovsky, VA ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2000年 / 49卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

aliphatic nitro compounds; silyl nitronates; N; N-bis(silyloxy)enamines; nitroso alkenes;

D O I：

10.1007/BF02494712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new alpha,beta-C,C-cross-coupling reaction of derivatives of aliphatic nitro compounds, silyl nitronates and N, N-bis(silyloxy)enamines, leading to beta-nitro oximes was found. The scope and limitations of this reaction were studied, and a mechanism was proposed.

引用

页码：874 / 878

页数：5

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