Polymeric monolithic materials: Syntheses, properties, functionalization and applications

被引:231
作者
Buchmeiser, Michael R.
机构
[1] Leibniz Inst Oberflachenmodifizierung eV, D-04318 Leipzig, Germany
[2] Univ Leipzig, Inst Chem Tech, D-04103 Leipzig, Germany
关键词
monolithic materials; polymer materials; polymer synthesis;
D O I
10.1016/j.polymer.2007.02.045
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthetic particularities for the synthesis of polymer-based monolithic materials are summarized. In this context, monoliths prepared via thermal-, UV- or electron-beam triggered free radical polymerization, controlled TEMPO-mediated radical polymerization, polyaddition, polycondensation as well as living ring-opening metathesis polymerization (ROMP) will be covered. Particular attention is devoted to the aspects of controlling pore sizes, pore volumes and pore size distributions as well as functionalization of these supports. Finally, selected, recent applications in separation science, (bio-) catalysis and chip technology will be summarized. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2187 / 2198
页数:12
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