Lithiumboryl - A synthon for a nucleophilic boryl anion

被引：70

作者：

Braunschweig, Holger ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

boron; boryl compounds; organoboranes;

D O I：

10.1002/anie.200605053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

B negative: By reduction of a 2-bromo-1,3,2-diazaborole Yamashita, Nozaki, and co-workers have obtained the first three-coordinate boryl anion (see formula), which provides an unprecedented and synthetically highly useful source for a nucleophilic boron species. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1946 / 1948

页数：3

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