Apparent contrast reversal in tapping mode atomic force microscope images on films of polystyrene-b-polyisoprene-b-polystyrene

被引:33
作者
Pickering, JP [1 ]
Vancso, GJ [1 ]
机构
[1] Univ Twente, Fac Chem Technol, NL-7500 AE Enschede, Netherlands
关键词
Atomic Force Microscope; Block Copolymer; Atomic Force Microscope Image; Amplitude Ratio; Contrast Variation;
D O I
10.1007/s002890050289
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Thin films of phase separated polystyrene-b-polyisoprene-b-polystyrene block copolymers were studied by tapping mode atomic force microscopy. The relative contrast in height and phase mode images of the phase separated regions was found to be very sensitive to changes in the operating conditions of the microscope. Contrast variations and reversals were observed for height and phase mode images as a function of the setpoint amplitude ratio and drive frequency. No unique height or phase contrast was observed for the the tri-block copolymer system examined in this study.
引用
收藏
页码:549 / 554
页数:6
相关论文
共 20 条
[1]   IMAGING AND MODIFICATION OF POLYMERS BY SCANNING TUNNELING AND ATOMIC FORCE MICROSCOPY [J].
ALBRECHT, TR ;
DOVEK, MM ;
LANG, CA ;
GRUTTER, P ;
QUATE, CF ;
KUAN, SWJ ;
FRANK, CW ;
PEASE, RFW .
JOURNAL OF APPLIED PHYSICS, 1988, 64 (03) :1178-1184
[2]   Factors affecting the height and phase images in tapping mode atomic force microscopy. Study of phase-separated polymer blends of poly(ethene-co-styrene) and poly(2,6-dimethyl-1,4-phenylene oxide) [J].
Bar, G ;
Thomann, Y ;
Brandsch, R ;
Cantow, HJ ;
Whangbo, MH .
LANGMUIR, 1997, 13 (14) :3807-3812
[3]  
Binggeli M., 1993, Nanotechnology, V4, P59, DOI 10.1088/0957-4484/4/2/001
[4]   How does a tip tap? [J].
Burnham, NA ;
Behrend, OP ;
Oulevey, F ;
Gremaud, G ;
Gallo, PJ ;
Gourdon, D ;
Dupas, E ;
Kulik, AJ ;
Pollock, HM ;
Briggs, GAD .
NANOTECHNOLOGY, 1997, 8 (02) :67-75
[5]  
DIJK MA, 1995, MACROMOLECULES, V28, P6773
[6]  
DUFENE YF, 1997, LANGMUIR, V13, P4779
[7]   MACRO-LATTICE FROM SEGREGATED AMORPHOUS PHASES OF A 3 BLOCK COPOLYMER [J].
KELLER, A ;
PEDEMONTE, E ;
WILLMOUTH, FM .
NATURE, 1970, 225 (5232) :538-+
[8]   RECONSTRUCTION OF STM AND AFM IMAGES DISTORTED BY FINITE-SIZE TIPS [J].
KELLER, D .
SURFACE SCIENCE, 1991, 253 (1-3) :353-364
[9]   Identification and visualization of questionable regions in atomic force microscope images [J].
Leung, ECW ;
Markiewicz, P ;
Goh, MC .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1997, 15 (02) :181-185
[10]   Characterization of polymer surfaces with atomic force microscopy [J].
Magonov, SN ;
Reneker, DH .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1997, 27 :175-222