Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes

被引：27

作者：

Sur, UK

Marken, F ^{[1
]}

Coles, BA

Compton, RG

Dupont, J

机构：

[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

[2] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[3] UFRGS, IQ, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b410655e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-focusing of intense microwave radiation at the tip of a 25 mm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM+PF6-) containing 1 mM ferrocene causes dramatically ( two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K ( at the electrode surface) - extreme conditions sufficient for condensed phase pyrolysis processes to occur.

引用

页码：2816 / 2817

页数：2

共 31 条

[1] Catalytic cracking reactions of polyethylene to light alkanes in ionic liquids [J].