Hydrothermal synthesis of a novel three-dimensional complex with strong blue luminescent properties

被引:36
作者
Ding, B
Yi, L
Liu, Y
Cheng, P [1 ]
Dong, YB
Ma, HP
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Shandong Normal Univ, Coll Chem, Shandong Key Lab Chem Funct Mat, Jinan 250014, Peoples R China
基金
中国国家自然科学基金;
关键词
hydrothermal synthesis; coordination polymer; fluorescent; Ag chain;
D O I
10.1016/j.inoche.2004.10.018
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with Ag2O under hydrothermal condition gave a novel complex [Ag-4(HBTC)(2)] (1). The X-ray crystal structural analysis indicates that 1 is a 3D coordinated framework, which contains zigzag Ag chains. Fluorescent analyses of 1 show intense blue photoluminescence at 453 nm in the solid state and may be potential candidates for photoactive material. (C) 2004 Published by Elsevier B.V.
引用
收藏
页码:38 / 40
页数:3
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