A comparative analysis between temperature and pressure measurements for early detection of runaway initiation

In this work, we have analysed the use of pressure instead of temperature measurements for the early warning detection of runaway initiation. This is possible due to the fact that our runaway criterion, i.e. div > 0, does not depend specifically on which state space variable we are using for divergence calculation. A series of runaway experiments, carried out in a 250 1 pilot-scale reactor, has been used to compare the results. In accordance with previous analysis, we show that by using temperature, early detection of runaway initiation is achieved. Analogously to temperature, pressure may be also used for runaway detection. By comparing the different types of reactive systems analysed (vapour and gassy), it can be observed that temperature works better, in terms of earlier detection, than pressure but the differences are more pronounced for vapour than for gassy systems. (C) 2004 Elsevier Ltd. All rights reserved.