Electrochemical characteristics of LiMxFe1-xPO4 cathode with LiBOB based electrolytes

被引：29

作者：

Wang, Sai ^{[1
]}

Qiu, Weihua ^{[1
]}

Guan, Yunlong ^{[1
]}

Yu, Bitao ^{[1
]}

Zhao, Hailei ^{[1
]}

Liu, Wei ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Dept Inorgan Nonmet Mat, Beijing 100083, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2007年 / 52卷 / 15期

基金：

中国国家自然科学基金;

关键词：

lithium-ion battery; electrolyte; LiBOB; bis(oxalato)borate; lithium iron phosphate;

D O I：

10.1016/j.electacta.2007.01.052

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The conductivity of LiBOB based electrolyte, which we formed in our lab, has been compared with commercialized LiPF6 based electrolyte firstly. The charge and discharge capacity of the LiFePO4/Li half-cell with two kind of electrolyte has compared both at room temperature and elevated temperature. LiBOB cell presented better charge/discharge stability at elevated temperature than the counterpart. ICP method was adopted to analyze the reaction of electrolytes with cathode material at high temperature. Cyclic voltammogram was conducted to analyze the charge/discharge process of the cell in both LiBOB based electrolyte and LiPF6 based electrolyte at different temperature. (c) 2007 Published by Elsevier Ltd.

引用

页码：4907 / 4910

页数：4

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