Encapsulation of catalysts in supramolecular porous frameworks: Size- and shape-selective catalytic oxidation of phenols

被引：76

作者：

Qiu, LG ^{[1
]}

Xie, AJ

Zhang, LD

机构：

[1] Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China

[2] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 06期

关键词：

D O I：

10.1002/adma.200400663

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel strategy for designing and synthesizing porous supramolecular catalysts is presented. Metal complexes encapsulated in three-dimensional hydrogen-bonded porous frameworks (see Figure) via self-assembly catalyze phenol oxidation. The catalysis is enhanced by the constraining effect of the channels formed in the supramolecular frameworks, and is significantly size- and shape-selective.

引用

页码：689 / +

页数：5