A new ruthenium-catalyzed reaction with propargyl alcohol: Cyclopropanation of norbornene

被引:29
作者
Kikuchi, H [1 ]
Uno, M [1 ]
Takahashi, S [1 ]
机构
[1] Osaka Univ, Inst Sci & Ind Res, Osaka 567, Japan
关键词
COMPLEXES;
D O I
10.1246/cl.1997.1273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cationic (eta(5)-cyclopentadienyl)tris(acetonitrile)ruthenium complexes catalyze a new reaction of propargyl alcohol with norbornene in methanol to give a cyclopropanation product, acetyltricyclooctane, in a quantitative yield.
引用
收藏
页码:1273 / 1274
页数:2
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