A new ruthenium-catalyzed reaction with propargyl alcohol: Cyclopropanation of norbornene

被引：29

作者：

Kikuchi, H ^{[1
]}

Uno, M ^{[1
]}

Takahashi, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 567, Japan

来源：

CHEMISTRY LETTERS | 1997年 / 12期

关键词：

COMPLEXES;

D O I：

10.1246/cl.1997.1273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic (eta(5)-cyclopentadienyl)tris(acetonitrile)ruthenium complexes catalyze a new reaction of propargyl alcohol with norbornene in methanol to give a cyclopropanation product, acetyltricyclooctane, in a quantitative yield.

引用

页码：1273 / 1274

页数：2

共 14 条

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[14] ON AN (OXATRIMETHYLENEMETHANE)PALLADIUM(0) COMPLEX - AN UNUSUAL PALLADIUM(0)-CATALYZED CYCLOPROPANATION
TROST, BM
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) : 4430 - 4433

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