The dissociative recombination of hydrocarbon ions. II. Alkene and alkyne derived species

被引：29

作者：

Rebrion-Rowe, C ^{[1
]}

Lehfaoui, L ^{[1
]}

Rowe, BR ^{[1
]}

Mitchell, JBA ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6627, F-35042 Rennes, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 17期

关键词：

D O I：

10.1063/1.476135

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dissociative recombination reactions of a number of cyclic ions, derived from ion-molecule reactions involving acetylene as parent molecule and of protonated butane derived from reactions involving ethylene have been studied. It is found that the recombination rate coefficient does not seem to be much affected by the substitution of functional groups for hydrogen atoms in the cyclic cases. Also, protonated butane has a rate coefficient very similar to that for protonated methane. (C) 1998 American Institute of Physics.

引用

页码：7185 / 7189

页数：5

共 22 条

[1]

ABOUELAZIZ H, 1993, J CHEM PHYS, V98, P1

[2] MEASUREMENTS OF DISSOCIATIVE RECOMBINATION COEFFICIENTS OF H-3+, HCO+, N2H+, AND CH5+ AT 95-K AND 300-K USING THE FALP APPARATUS [J].

ADAMS, NG ;

SMITH, D ;

ALGE, E .

JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (04) :1778-1784

[3]

BRUNETTI B, 1993, AIP C P, V295, P623

[4] MECHANISMS OF SOOT NUCLEATION IN FLAMES - A CRITICAL-REVIEW [J].

CALCOTE, HF .

COMBUSTION AND FLAME, 1981, 42 (03) :215-242

[5] Density functional studies of carbonium ions [J].

Collins, SJ ;

OMalley, PJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (22) :4347-4355

[6] The C4H5+ potential energy surface. Structure, relative energies, and enthalpies of formation of isomers of C4H5+ [J].

Cunje, A ;

Rodriquez, CF ;

Lien, MH ;

Hopkinson, AC .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (16) :5212-5220

[7] CHEMIIONIZATION AND ION MOLECULE REACTIONS IN FUEL-RICH ACETYLENE FLAMES [J].

ERASLAN, AN ;

BROWN, RC .

COMBUSTION AND FLAME, 1988, 74 (01) :19-37

[8]

FOX JL, 1995, DISSOCIATIVE RECOMBI, V3, P40

[9]

HERBST E, 1995, ANNU REV PHYS CHEM, V46, P27, DOI 10.1146/annurev.pc.46.100195.000331

[10]

Ikezoe Y., 1987, Gas Phase Ion-Molecule Reaction Rate Constants through 1986

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