The dissociative recombination of hydrocarbon ions. II. Alkene and alkyne derived species

被引:29
作者
Rebrion-Rowe, C [1 ]
Lehfaoui, L [1 ]
Rowe, BR [1 ]
Mitchell, JBA [1 ]
机构
[1] Univ Rennes 1, CNRS, UMR 6627, F-35042 Rennes, France
关键词
D O I
10.1063/1.476135
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dissociative recombination reactions of a number of cyclic ions, derived from ion-molecule reactions involving acetylene as parent molecule and of protonated butane derived from reactions involving ethylene have been studied. It is found that the recombination rate coefficient does not seem to be much affected by the substitution of functional groups for hydrogen atoms in the cyclic cases. Also, protonated butane has a rate coefficient very similar to that for protonated methane. (C) 1998 American Institute of Physics.
引用
收藏
页码:7185 / 7189
页数:5
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