A simplified synthesis of (+/-)-1,2-diphenyl-1,2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates ''hydrobenzamide'' and ''amarine''

被引:60
作者
Corey, EJ
Kuhnle, FNM
机构
[1] Dept. of Chem. and Chemical Biology, Harvard University, Cambridge
关键词
D O I
10.1016/S0040-4039(97)10372-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new pathway for the simple, stereocontrolled and economical synthesis of (+/-)-1 from benzaldehyde is described. The structures of two intermediates (Scheme 1) have been revised to those shown in Scheme 2. (C) 1997 Elsevier Science Ltd.
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页码:8631 / 8634
页数:4
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