Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids

被引：64

作者：

Guchhait, Sankar K. ^{[1
]}

Kashyap, Maneesh ^{[1
]}

Saraf, Shuddham ^{[1
]}

机构：

[1] NIPER, Dept Med Chem, Sector 67, Sas Nagar 160062, Punjab, India

来源：

SYNTHESIS-STUTTGART | 2010年 / 07期

关键词：

cross-coupling; direct arylation; biaryls; single-electron transfer; microwave; CATALYZED DIRECT ARYLATION; MANGANESE(III) ACETATE; COUPLING REACTION; ARENES; BIARYLS; FUNCTIONALIZATION; PHENYLHYDRAZINES; CYCLODEHYDRATION; PHOSPHONATION; HETEROARENES;

D O I：

10.1055/s-0029-1219234

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel microwave-promoted protocol mediated by Mn(OAc)(3) was developed for the single-electron-transfer oxidative direct C-H bond arylation of (hetero)arenes with aryl and heteroarylboronic acids. Various electron-deactivated and electron-rich heteroarenes and benzene underwent successfully the direct arylation in this general process. The use of slight excess of heteroarene or benzene in this method was found to be sufficient.

引用

页码：1166 / 1170

页数：5

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