C5H14NO•ZnCl(HPO3), an unexpected product from an ionic-liquid synthesis

被引:17
作者
Harrison, William T. A. [1 ]
机构
[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland
关键词
hybrid solids; ionic liquids; zinc; phosphorus;
D O I
10.1016/j.inoche.2007.04.010
中图分类号
O61 [无机化学];
学科分类号
070301 [无机化学]; 081704 [应用化学];
摘要
C5H14NO center dot ZnCl(HPO3) arose from an unexpected reaction in which a component of the ionic liquid mixed solvent was incorporated into a hybrid structure in which cholinium (C5H14NO+) cations interact with [ZnCl(HPO3)](-) macroanionic layers by way of O-H...O hydrogen bonds. The inorganic layers display a 4 . 8(2) topology. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:833 / 835
页数:3
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