Eighty years of polarography - History and future

被引:40
作者
Barek, J [1 ]
Zima, J [1 ]
机构
[1] Charles Univ Prague, Dept Analyt Chem, Lab Environm Electrochem, UNESCO, Prague 12843 2, Czech Republic
关键词
polarography; voltammetry; mercury electrodes; history;
D O I
10.1002/elan.200390055
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Since 1922, when Professor Jaroslav Heyrovsky carried out his pioneering experiment with a dropping mercury electrode, polarography showed remarkable ability to adjust to ever increasing demands on the sensitivity and selectivity and up to now mercury electrodes are among the best sensors for electroanalytical measurements. The aim of this contribution is to show both the historical development of these techniques and their presence and possible future developments and to show that even today in certain cases polarographic and voltammetric techniques on mercury electrodes can successfully compete with modern separation and spectrometric techniques.
引用
收藏
页码:467 / 472
页数:6
相关论文
共 54 条
[21]  
Kalousek M., 1948, COLLECT CZECH CHEM C, V13, P105
[22]  
Kalvoda R., 1965, TECHNIQUES OSCILLOGR
[23]   APPLICATION DE LA GOUTTE PENDANTE DE MERCURE A LA DETERMINATION DE MINIMES QUANTITES DE DIFFERENTS IONS [J].
KEMULA, W ;
KUBLIK, Z .
ANALYTICA CHIMICA ACTA, 1958, 18 (1-2) :104-111
[24]   STRIPPING ANALYSIS ON CONTROLLED-GROWTH MERCURY DROP ELECTRODE [J].
KOWALSKI, Z ;
MIGDALSKI, J .
ELECTROANALYSIS, 1992, 4 (09) :915-919
[25]   INCREASING THE SIGNAL-TO-NOISE RATIO IN AMPEROMETRY AND POLAROGRAPHY USING THE CONTROLLED-GROWTH MERCURY DROP ELECTRODE [J].
KOWALSKI, Z ;
MIGDALSKI, J .
TALANTA, 1994, 41 (02) :309-316
[26]   Bismuth-film-plated carbon paste electrodes [J].
Królicka, A ;
Pauliukaite, R ;
Svancara, I ;
Metelka, R ;
Bobrowski, A ;
Norkus, E ;
Kalcher, K ;
Vytras, K .
ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (02) :193-196
[27]  
Kubicárová T, 2000, ELECTROANAL, V12, P1390, DOI 10.1002/1521-4109(200011)12:17<1390::AID-ELAN1390>3.0.CO
[28]  
2-G
[29]  
Migdalski J, 1999, CHEM ANAL-WARSAW, V44, P635
[30]  
MURRAY RW, 1984, ELECTROANALYTICAL CH, V13, pCH3