Modelling of magneto-chiral enantioselective photochemistry

被引：23

作者：

Raupach, E

Rikken, GLJA

Train, C

Malézieux, B

机构：

[1] Max Planck Inst Festkorperforsch, Grenoble High Magnet Field Lab, CNRS, F-38042 Grenoble, France

[2] Univ Paris 06, Lab Chim Inorgan & Mat Mol, F-75252 Paris, France

来源：

CHEMICAL PHYSICS | 2000年 / 261卷 / 03期

关键词：

D O I：

10.1016/S0301-0104(00)00284-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present a kinetic model to describe the recently observed magneto-chiral enantioselective photochemistry when irradiating with unpolarized light and applying a static magnetic field. The model shows that both true and cascaded magneto-chiral enantioselective photochemistry occur and yields expressions for their respective magnitudes. Comparison of the predictions of our model with the experimental results shows good agreement. (C) 2000 Published by Elsevier Science B.V.

引用

页码：373 / 380

页数：8

共 11 条

[1]

[Anonymous], 1969, MOL PHOTOCHEM

[2] Absolute asymmetric synthesis under physical fields: Facts and fictions [J].