Novel cationic chiral phosphorus ligands and their zwitterionic hydridocarbonylferrate complexes

被引：24

作者：

Brunet, JJ ^{[1
]}

Chauvin, R ^{[1
]}

Commenges, G ^{[1
]}

Donnadieu, B ^{[1
]}

Leglaye, P ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 07期

关键词：

D O I：

10.1021/om9508804

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (-)-N,N-dimethylephedrinium salts with R(2)PNMe(2) derivatives allows the high-yield synthesis of new chiral phosphorus ligands with an ammonium side chain, termed ''ephosiums''. Diphenyl-N,N-dimethylephosium hexaflurophosphate reacts with KHFe(CO)(4) to afford the chiral zwitterionic complex diphenyl-N,N-dimethylephosium hydridotricarbonylferrate, characterized by X-ray diffraction and NMR studies.

引用

收藏

页码：1752 / 1754

页数：3

相关论文

共 26 条

[21] THIOLATE, THIOETHER, AND THIOL DERIVATIVES OF IRON(0) CARBONYLS [J].

LIAW, WF ;

KIM, C ;

DARENSBOURG, MY ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3591-3597

[22]

ODonnell M. J., 1993, CATALYTIC ASYMMETRIC, P389

[23] CHEMISTRY OF HYDRIDO CARBONYL-6B METALATES SUBSTITUTED BY P-DONOR LIGANDS - HW(CO)4PME3- HW(CO)4POME3- HW(CO)4PPH3- AND MU-H[WM(CO)10-X(P(OME)3)X] (M=CR,W - X=1,2) [J].

SLATER, SG ;

LUSK, R ;

SCHUMANN, BF ;

DARENSBOURG, M .

ORGANOMETALLICS, 1982, 1 (12) :1662-1666

[24] ANIONIC GROUP-6 HYDRIDES AND CARBOXYLATES AS HOMOGENEOUS CATALYSTS FOR REDUCTION OF ALDEHYDES AND KETONES [J].

TOOLEY, PA ;

OVALLES, C ;

KAO, SC ;

DARENSBOURG, DJ ;

DARENSBOURG, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) :5465-5470

[25] INTRAMOLECULAR PHOSPHINE ATTACK ON A COORDINATED ALKYNE LIGAND IN CO2(CO)4(BMA)(MU-PHCCH) - CHARACTERIZATION OF THE ZWITTERIONIC HYDROCARBYL COMPLEX CO2(CO)4[MU-ETA-2-ETA-2-ETA-1-ETA-1-PHC=C(H)PPH2 CYCLO (C=C(PPH2)C(O)OC)(O)] [J].

YANG, KY ;

BOTT, SG ;

RICHMOND, MG .

ORGANOMETALLICS, 1994, 13 (10) :3767-3769

[26] ZWITTERIONIC RHODIUM(I) COMPLEX-CATALYZED NET SILYLHYDROFORMYLATION OF TERMINAL ALKYNES [J].

ZHOU, JQ ;

ALPER, H .

ORGANOMETALLICS, 1994, 13 (05) :1586-1591