Salicylhydrazone ligands for enantioselective addition of diethylzinc to aldehydes

被引：14

作者：

Arai, Takayoshi ^{[1
]}

Endo, Yoko

Yanagisawa, Akira

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Chiba 2638522, Japan

[2] Chiba Univ, Grad Sch Sci & Technol, Chiba 2638522, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2007年 / 18卷 / 02期

关键词：

D O I：

10.1016/j.tetasy.2007.01.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of chiral salicylhydrazones was designed and synthesized for application in asymmetric catalysis. The ability of newly prepared binaphthyl-containing salicylhydrazones as the chiral ligand was examined in the addition of diethylzinc to aldehyde, with the desired product obtained in up to 80% ee. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：165 / 169

页数：5

共 36 条

[1] Asymmetric catalysis of carbon-carbon bond-forming reactions using metal(salen) complexes [J].