Responsive polyelectrolyte multilayers

被引:102
作者
Glinel, Karine [1 ]
Dejugnat, Christophe
Prevot, Michelle
Schoeler, Bjoern
Schoenhoff, Monika
Klitzing, Regine V.
机构
[1] Univ Rouen, CNRS, UMR 6522, Lab Polymeres Biopolymeres Membranes, F-76821 Mont St Aignan, France
[2] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[3] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany
[4] Inst Chem, Stranski Lab, D-10623 Berlin, Germany
[5] Inst Chim Separat Marcoule, F-30207 Bagnols Sur Ceze, France
关键词
layer-by-layer assembly; responsive film; polyelectrolyte microcapsule; poly(N-isopropylacrylamide); weak polyelectrolyte;
D O I
10.1016/j.colsurfa.2007.02.052
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this review we present selected recent developments of responsive multilayers formed by layer-by-layer assembly of oppositely charged polymers, with particular emphasis on the preparation of temperature- and pH-sensitive systems. We discuss the influence of the architecture and of the nature of the polyelectrolytes used on the responsive behavior of the films. Different strategies based on polyelectrolyte shells or films incorporating stimuli-responsive polyelectrolytes are reviewed as well as the entrapment of stimuli-responsive polymer into hollow capsules. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:3 / 13
页数:11
相关论文
共 67 条
[11]   Defined picogram dose inclusion and release of macromolecules using polyelectrolyte microcapsules [J].
Déjugnat, C ;
Halozan, D ;
Sukhorukov, GB .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (12) :961-967
[12]   PH-responsive properties of hollow polyelectrolyte microcapsules templated on various cores [J].
Déjugnat, C ;
Sukhorukov, GB .
LANGMUIR, 2004, 20 (17) :7265-7269
[13]  
DEJUGNAT C, 2006, RESPONSIVE POLYMER M
[14]   Observation of the volume transition in thermosensitive core-shell latex particles by small-angle X-ray scattering [J].
Dingenouts, N ;
Norhausen, C ;
Ballauff, M .
MACROMOLECULES, 1998, 31 (25) :8912-8917
[15]  
Donath E, 1998, ANGEW CHEM INT EDIT, V37, P2202, DOI 10.1002/(SICI)1521-3773(19980904)37:16<2201::AID-ANIE2201>3.0.CO
[16]  
2-E
[17]   EFFECT OF COMONOMER HYDROPHILICITY AND IONIZATION ON THE LOWER CRITICAL SOLUTION TEMPERATURE OF N-ISOPROPYLACRYLAMIDE COPOLYMERS [J].
FEIL, H ;
BAE, YH ;
FEIJEN, J ;
KIM, SW .
MACROMOLECULES, 1993, 26 (10) :2496-2500
[18]   Salt effects on the thermoprecipitation of poly-(N-isopropylacrylamide) oligomers from aqueous solution [J].
Freitag, R ;
Garret-Flaudy, F .
LANGMUIR, 2002, 18 (09) :3434-3440
[19]   Influence of polyelectrolyte charge density on the formation of multilayers of strong polyelectrolytes at low ionic strength [J].
Glinel, K ;
Moussa, A ;
Jonas, AM ;
Laschewsky, A .
LANGMUIR, 2002, 18 (04) :1408-1412
[20]   Thermosensitive hollow capsules based on thermoresponsive polyelectrolytes [J].
Glinel, K ;
Sukhorukov, GB ;
Möhwald, H ;
Khrenov, V ;
Tauer, K .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (14) :1784-1790