Divalent metal 1,3-phenylenediacetate coordination polymers with rigid or flexible dipyridyl tethers: Chains, layers, and interpenetrated networks

被引:17
作者
Blake, Karyn M. [1 ,2 ]
Johnston, Lindsey L. [1 ,2 ]
Braverman, Maxwell A. [1 ,2 ]
Nettleman, Joseph H. [1 ,2 ]
Sposato, Laura K. [3 ]
LaDuca, Robert L. [1 ,2 ]
机构
[1] Michigan State Univ, Lyman Briggs Coll, E Lansing, MI 48825 USA
[2] Michigan State Univ, Dept Chem, E Lansing, MI 48825 USA
[3] Kings Coll, Dept Chem & Phys, Wilkes Barre, PA 18711 USA
关键词
Cobalt; Nickel; Copper; X-ray crystal structures; Coordination polymer; Antiferromagnetism; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; HELICAL CHAINS; LIGAND; SEPARATION; HYDROGEN; DESIGN; CONSTRUCTION; FLUORESCENCE;
D O I
10.1016/j.ica.2010.03.029
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrothermal synthesis has afforded four divalent metal 1,3-phenylenediacetate (1,3-phda) coordination polymers containing different dipyridyl-type ligands. {[Cu(1,3-phda)(dpa)(H2O)]center dot H2O}(n) (1, dpa = 4,4'-dipyridylamine) exhibits a simple 2-D (4,4) rhomboid grid structure. {[Co(1,3-phda)(bpy)]center dot 1.5H(2)O}(n) (2, bpy = 4,4'-bipyridine) also possesses a (4,4) layer structure, but with syn-syn bridged {Co-2(OCO)(2)} dimeric kernels serving as 4-connected nodes. {[Co(H2O)(4)(3-bpmpH(2))](1,3-phda)(2)center dot 8H(2)O}(n) (3, 3-bpmp = bis(3-pyridylmethyl) piperazine) manifests cationic 1-D [Co(H2O)(4)(3-bpmpH(2))](n)(4n+) chains linked into higher dimensionality by unligated 1,3-phda anions and curled tetrameric water molecule units. {[Ni(1,3-phda)(4-bpmp)(H2O)(2)]center dot 2H(2)O}(n) (4,4-bpmp = bis(4-pyridylmethyl) piperazine) has an underlying twofold interpenetrated 6(5)8 (cds) 3-D network topology. Variable temperature magnetic susceptibility studies revealed the presence of weak antiferromagnetic coupling and zero-field splitting (J = -1.65(4) cm(-1) and D = 30.9(7) cm(-1) with g = 2.20(1)) within the {Co-2(OCO)(2)} dimers in 2. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2233 / 2242
页数:10
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