Highly ordered mesoporous silicon oxynitride materials as base catalysts

被引:136
作者
Xia, YD [1 ]
Mokaya, R [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
basicity; heterogeneous catalysis; knoevenagel condensation; mesoporous materials; silicon;
D O I
10.1002/anie.200350978
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Basically, a good catalyst: The introduction of NHx species into the framework of mesoporous silicas results in silicon oxynitride materials and generates basic sites, which exhibit considerable catalytic activity for the Knoevenagel condensation reaction (see scheme). The well-ordered mesoporous oxynitrides have a high surface area and pore volume and are attractive as alternative basic catalysts, especially for large-molecule transformations.
引用
收藏
页码:2639 / 2644
页数:6
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