Synthesis of 2-furfurylmaleimide and preliminary study of its Diels-Alder polycondensation

被引：33

作者：

Gousse, C ^{[1
]}

Gandini, A ^{[1
]}

机构：

[1] Ecole Francaise Papeterie & Ind Graph, INPG, F-38402 St Martin Dheres, France

来源：

POLYMER BULLETIN | 1998年 / 40卷 / 4-5期

关键词：

Sodium; Acetate; Hydrolysis; Anhydride; Sodium Acetate;

D O I：

10.1007/s002890050267

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

2-furfurylmaleimide (FM) was synthesized and characterized unambiguously for the first time by condensing 2-furfurylamine with maleic anhydride to give the corresponding maleamic acid which was in turn cyclized in the presence of acetic anhydride and sodium acetate. A thorough structural assessment was carried out to prove the success of this procedure. FM is highly sensitive to ring-opening hydrolysis by atmospheric moisture and must be kept ina dry medium. This investigation was aimed at using FM as an AB-type monomer in a polycondensation based on the Diels-Alder reaction. Preliminary experiments are reported on this novel system which provided the first polycondensates of this kind.

引用

页码：389 / 394

页数：6

共 6 条

[1]

DELAIRE M, 1969, Patent No. 2031538

[2] Furans in polymer chemistry [J].

Gandini, A ;

Belgacem, MN .

PROGRESS IN POLYMER SCIENCE, 1997, 22 (06) :1203-1379

[3] Acetalization of polyvinyl alcohol with furfural [J].

Gousse, C ;

Gandini, A .

EUROPEAN POLYMER JOURNAL, 1997, 33 (05) :667-671

[4]

GOUSSE C, 1997, THESIS GRENOBLE POLY

[5]

GOUSSE C, 1997, IN PRESS MACROMOLECU

[6] SYNTHESIS AND DIELS-ALDER POLYMERIZATION OF FURFURYLIDENE AND FURFURYL-SUBSTITUTED MALEAMIC ACIDS [J].

MIKROYANNIDIS, JA .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (01) :125-132

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