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Isomerization of α-pinene over ion-exchanged natural zeolites
被引:43
作者:
Özkan, F
Gündüz, G
Akpolat, O
Besün, N
Murzin, DY
机构:
[1] Izmir Inst Technol, Dept Chem Engn, TR-35437 Urla, Izmir, Turkey
[2] Ege Univ, Dept Chem Engn, Izmir, Turkey
[3] Ege Univ, Dept Bioengn, Izmir, Turkey
[4] Abo Akad Univ, Lab Ind Chem, Proc Chem Grp, Turku, Finland
关键词:
isomerization;
alpha-pinene;
clinoptilolite;
ion-exchange;
D O I:
10.1016/S1385-8947(02)00162-6
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Catalysts prepared by ion exchange of clinoptilolite-based natural zeolite tuffs; with NH4+, Ba2+ and Pb2+ were investigated in the isomerization reaction of alpha-pinene at atmospheric pressure under nitrogen flow. Activity and selectivity to mono-, bi- and tricyclic products were correlated with acidity strength. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:257 / 269
页数:13
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