1D chain and 3D framework of silver(I) organo-metallic polymers self-assembled with triptycene

被引：13

作者：

Wen, Ming

Munakata, Megumu

Li, Yi-Zhi

Suenaga, Yusaku

Kuroda-Sowa, Takayoshi

Maekawa, Masahiko

Anahata, Manabu

机构：

[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China

[2] Kinki Univ, Dept Chem, Higashiosaka, Osaka 577, Japan

[3] Nanjing Univ, Coordinat Chem Inst, State Key Lab Coordinat, Nanjing 210093, Peoples R China

[4] Kinki Univ, Res Inst Sci & Technol, Higashiosaka, Osaka 577, Japan

来源：

POLYHEDRON | 2007年 / 26卷 / 12期

关键词：

silver(I) complex; triptycene; porous complex;

D O I：

10.1016/j.poly.2006.12.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the purpose of investigating the coordination behavior of sterically congested alkenes and exploring the possibility of non-planar complexation in the polycyclic aromatic system for formation of extended polymeric networks, triptycene (tpty) has been studied with regard to its complexation with the silver(I) ion. The crystal structures of [Ag(tpty)(THF)(2)](ClO4) (1) and [Ag-6(tPtY)(4)(CF3SO3)(2-)(H2O)(6)](CF3SO3)(4) (2) have been determined by single-crystal X-ray diffraction. The polycyclic aromatic hydrocarbon triptycene is found to offer a potential site for complexation, which can be utilized to generate an interesting array of organo-metallic polymers with one-dimensional (1D) chain and three-dimensional (3D) porous frameworks. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2455 / 2460

页数：6

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