Direct ethanol fuel cells with catalysed metal mesh anodes

被引:42
作者
Chetty, Raghuram [1 ]
Scott, Keith [1 ]
机构
[1] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
基金
英国工程与自然科学研究理事会;
关键词
ethanol; oxidation; electrocatalyst; fuel cells; thermal decomposition;
D O I
10.1016/j.electacta.2006.11.043
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Platinum based binary and ternary catalysts prepared by thermal decomposition on titanium mesh were characterised and compared in terms of the electrochemical activity for ethanol oxidation. An enhancement in the catalytic activity was observed for the binary catalyst containing tin and ruthenium in their compositions with platinum. The catalysts were tested in single direct ethanol fuel cells and the result obtained with PtRu and PtSn showed that the mesh based electrodes show competitive performance in comparison to the conventional carbon based anodes. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4073 / 4081
页数:9
相关论文
共 41 条
[1]   Novel anode structure for the direct methanol fuel cell [J].
Allen, RG ;
Lim, C ;
Yang, LX ;
Scott, K ;
Roy, S .
JOURNAL OF POWER SOURCES, 2005, 143 (1-2) :142-149
[2]  
Aricò AS, 1998, ELECTROCHEM SOLID ST, V1, P66, DOI 10.1149/1.1390638
[3]   Catalysis of ethanol electro oxidation by PtRu: the influence of catalyst composition [J].
Camara, GA ;
de Lima, RB ;
Iwasita, T .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (08) :812-815
[4]  
CHETTY R, 2004, THESIS U NEWCASTLE U
[5]   Effect of temperature on the mechanism of ethanol oxidation on carbon supported Pt, PtRu and Pt3Sn electrocatalysts [J].
Colmati, Flavio ;
Antolini, Ermete ;
Gonzalez, Ernesto R. .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :98-103
[6]   Ethanol oxidation on novel, carbon supported Pt alloy catalysts - Model studies under defined diffusion conditions [J].
Colmenares, L. ;
Wang, H. ;
Jusys, Z. ;
Jiang, L. ;
Yan, S. ;
Sun, G. Q. ;
Behm, R. J. .
ELECTROCHIMICA ACTA, 2006, 52 (01) :221-233
[7]   Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes. A study using DEMS and in-situ FTIR techniques [J].
de Souza, JPI ;
Queiroz, SL ;
Bergamaski, K ;
Gonzalez, ER ;
Nart, FC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (38) :9825-9830
[8]  
de Souza JPI, 2000, J APPL ELECTROCHEM, V30, P43
[9]   Enhancement of the electrooxidation of ethanol on a Pt-PEM electrode modified by tin.: Part I:: Half cell study [J].
Delime, F ;
Léger, JM ;
Lamy, C .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1999, 29 (11) :1249-1254
[10]   International activities in DMFC R&D:: status of technologies and potential applications [J].
Dillon, R ;
Srinivasan, S ;
Aricò, AS ;
Antonucci, V .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :112-126