Direct ethanol fuel cells with catalysed metal mesh anodes

被引：42

作者：

Chetty, Raghuram ^{[1
]}

Scott, Keith ^{[1
]}

机构：

[1] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ELECTROCHIMICA ACTA | 2007年 / 52卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

ethanol; oxidation; electrocatalyst; fuel cells; thermal decomposition;

D O I：

10.1016/j.electacta.2006.11.043

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Platinum based binary and ternary catalysts prepared by thermal decomposition on titanium mesh were characterised and compared in terms of the electrochemical activity for ethanol oxidation. An enhancement in the catalytic activity was observed for the binary catalyst containing tin and ruthenium in their compositions with platinum. The catalysts were tested in single direct ethanol fuel cells and the result obtained with PtRu and PtSn showed that the mesh based electrodes show competitive performance in comparison to the conventional carbon based anodes. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4073 / 4081

页数：9

共 41 条

[21] Characterisation of direct methanol fuel cells under near-ambient conditions [J].

Oedegaard, Anders .

JOURNAL OF POWER SOURCES, 2006, 157 (01) :244-252

[22] Direct ethanol fuel cell (DEFC):: Electrical performances and reaction products distribution under operating conditions with different platinum-based anodes [J].

Rousseau, S. ;

Coutanceau, C. ;

Lamy, C. ;

Leger, J. -M. .

JOURNAL OF POWER SOURCES, 2006, 158 (01) :18-24

[23] Direct ethanol PEM fuel cells: The case of platinum based anodes [J].

Song, SQ ;

Zhou, WJ ;

Zhou, ZH ;

Jiang, LH ;

Sun, GQ ;

Xin, Q ;

Leontidis, V ;

Kontou, S ;

Tsiakaras, P .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2005, 30 (09) :995-1001

[24] Recent progress in direct ethanol proton exchange membrane fuel cells (DE-PEMFCs) [J].

Song, SQ ;

Tsiakaras, P .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 63 (3-4) :187-193

[25] Co-catalytic effect of nickel in the electro-oxidation of ethanol on binary Pt-Sn electrocatalysts [J].

Spinacé, EV ;

Linardi, M ;

Neto, AO .

ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (04) :365-369

[26] Electro-oxidation of ethanol using PtRu/C electrocatalysts prepared by alcohol-reduction process [J].

Spinacé, EV ;

Neto, AO ;

Vasconcelos, TRR ;

Linardi, M .

JOURNAL OF POWER SOURCES, 2004, 137 (01) :17-23

[27] Preparation and evaluation of a multi-component catalyst by using a co-sputtering system for anodic oxidation of ethanol [J].

Tanaka, S ;

Umeda, M ;

Ojima, H ;

Usui, Y ;

Kimura, O ;

Uchida, I .

JOURNAL OF POWER SOURCES, 2005, 152 (01) :34-39

[28] On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies [J].

Vigier, F ;

Coutanceau, C ;

Hahn, F ;

Belgsir, EM ;

Lamy, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 563 (01) :81-89

[29] Development of anode catalysts for a direct ethanol fuel cell [J].

Vigier, F ;

Coutanceau, C ;

Perrard, A ;

Belgsir, EM ;

Lamy, C .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2004, 34 (04) :439-446

[30] Ethanol electro-oxidation on carbon-supported Pt, PtRu and Pt3Sn catalysts:: A quantitative DEMS study [J].

Wang, H ;

Jusys, Z ;

Behm, RJ .

JOURNAL OF POWER SOURCES, 2006, 154 (02) :351-359

← 1 2 3 4 5 →