Tetrathiophosphoric acid tri(1-phenylethyl) ester and 1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents

被引：26

作者：

Gigmes, D

Bertin, D

Marque, S

Guerret, O

Tordo, P

机构：

[1] Univ Aix Marseille 1, CNRS, UMR 6517,Ctr St Jerom, Lab Struct & React Especes Paramagnet, F-13397 Marseille 20, France

[2] Univ Aix Marseille 3, Ctr St Jerome, F-13397 Marseille, France

[3] ATOFINA, Grp Rech Lacq, F-64170 Lacq, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(02)02848-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polystyrene and polystyrene-b-polyvinylacetate have been prepared in presence of either tetrathiophosphoric acid tri(1-phenylethyl) ester 1 or 1-phenylethyl-diphenylphosphinodithioate 2 under radical conditions. From kinetic studies performed with or without 1 or 2, it was shown that the polymerization presents the criteria of living/controlled polymerization. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1227 / 1229

页数：3

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