Azobenzene derivatives with a long alkyl chain and aminoxyls

被引:13
作者
Fujino, M [1 ]
Amano, T [1 ]
Akutsu, H [1 ]
Yamada, J [1 ]
Nakatsuji, S [1 ]
机构
[1] Univ Hyogo, Grad Sch Mat Sci, Dept Mat Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1039/b408432b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A trans-azobenzene derivative with a long alkyl chain and a TEMPO radical showed photo-induced isomerization to become the corresponding cis-isomer with a significant change of its intermolecular magnetic interaction from a weak ferromagnetic one based on the CW model to a relatively strong antiferromagnetic one based on the ST model with the J-value of 36.7 K.
引用
收藏
页码:2310 / 2311
页数:2
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