Why are B2O2 rings rare?

被引：17

作者：

Burke, JM ^{[1
]}

Fox, MA ^{[1
]}

Goeta, AE ^{[1
]}

Hughes, AK ^{[1
]}

Marder, TB ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b006685k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single-crystal X-ray structure of {[HPPh3](+)}(2)[B4F10O2](2-) 2 reveals trigonal planar oxygen atoms in a rare example of a B2O2 ring; extended Huckel and ab initio molecular orbital calculations provide insight into the bonding and the geometry about oxygen.

引用

页码：2217 / 2218

页数：2

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