Synthesis of Halogenated Carboxylic Acids and Amino Acids

被引：50

作者：

Czekelius, Constantin ^{[1
]}

Tzschucke, Carl Christoph ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

SYNTHESIS-STUTTGART | 2010年 / 04期

关键词：

halogens; fluorine; trifluoromethylation; enantioselective methods; organocatalysis; BETA-KETO-ESTERS; CATALYTIC ENANTIOSELECTIVE FLUORINATION; CHIRAL PALLADIUM COMPLEXES; FRIEDEL-CRAFTS ALKYLATION; ASYMMETRIC ELECTROPHILIC FLUORINATION; N-FLUOROAMMONIUM SALTS; SILYL ENOL ETHERS; ORGANOCATALYTIC ALPHA-FLUORINATION; HIGHLY STEREOSELECTIVE-SYNTHESIS; QUATERNARY STEREOGENIC CENTERS;

D O I：

10.1055/s-0029-1218649

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

This review summarizes and focuses on stereoselective methods for the preparation of halogenated carboxylic acids and amino acids. Diastereoselective and enantioselective halogen atom transfer processes as well as methods for the synthesis of fluoroalkyl-substituted compounds are discussed in detail.

引用

页码：543 / 566

页数：24

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