The titanocene dicarbonyl dication [TiCp2(CO)(2)](2+)

被引：11

作者：

Calderazzo, F ^{[1
]}

Pampaloni, G ^{[1
]}

Tripepi, G ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 23期

关键词：

D O I：

10.1021/om970634n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two-electron oxidation of TiCp2(CO)(2) or double protonation of TiCp4 in toluene under carbon monoxide affords an exceedingly moisture-sensitive solid which has been isolated and identified as the tetraphenylborato derivative of the titanocene dicarbonyl dication [TiCp2(CO)(2)](2+) on the basis of both spectroscopic data and reactivity.

引用

页码：4943 / 4944

页数：2

共 39 条

[1] OXIDATION OF TETRAPHENYLBORATE BY HEXACHLOROIRIDATE(IV)
ABLEY, P
HALPERN, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (20): : 1238 - &
[2] DICARBONYLGOLD(I) HEXAFLUOROURANATE(VI), AU(CO)2UF6
ADELHELM, M
BACHER, W
HOHN, EG
JACOB, E
[J]. CHEMISCHE BERICHTE, 1991, 124 (07) : 1559 - 1561
[3] A THERMALLY STABLE CARBONYL COMPLEX OF ZIRCONIUM .4. STRUCTURE AND REACTIVITY RAMIFICATIONS OF STRONG DELTA[-PI-ASTERISK ELECTRON DONATION
ANTONELLI, DM
TJADEN, EB
STRYKER, JM
[J]. ORGANOMETALLICS, 1994, 13 (03) : 763 - 765
[4] CRYSTAL-STRUCTURE OF DICARBONYLDICYCLOPENTADIENYLTITANIUM(II), (ETA5-C5H5)2TI(CO)2
ATWOOD, JL
STONE, KE
ALT, HG
HRNCIR, DC
RAUSCH, MD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 132 (03) : 367 - 375
[5] SPEKTROSKOPISCHE UNTERSUCHUNGEN AN KOMPLEXVERB INDUNGEN .9. IR-INTENSITATEN VON CO- UND NO-VALENZSCHWINGUNGEN UND BINDUNGSWINKEL IN METALLCARBONYLEN UND -NITROSYLEN
BECK, W
MELNIKOF.A
STAHL, R
[J]. CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (12): : 3721 - &
[6] Synthesis and spectroscopic characterization of hexakis(carbonyl)iron(II) undecafluorodiantimonate(V), [Fe(CO)(6)][Sb2F11](2)
Bley, B
Willner, H
Aubke, F
[J]. INORGANIC CHEMISTRY, 1997, 36 (02) : 158 - 160
[7] Syntheses and vibrational and C-13 MAS-NMR spectra of bis(carbonyl)mercury(II) undecafluorodiantimonate(V) ([Hg(CO)(2)][Sb2F11](2)) and of bis(carbonyl) dimercury(I) undecafluorodiantimonate ([Hg-2(CO)(2)][Sb2F11](2)) and the molecular structure of [Hg(CO)(2)][Sb2F11](2)
Bodenbinder, M
BalzerJollenbeck, G
Willner, H
Batchelor, RJ
Einstein, FWB
Wang, C
Aubke, F
[J]. INORGANIC CHEMISTRY, 1996, 35 (01) : 82 - 92
[8] Synthesis and structure of donor-ligand-stabilized tris(cyclopentadienyl)zirconium cations
Brackemeyer, T
Erker, G
Frohlich, R
[J]. ORGANOMETALLICS, 1997, 16 (04) : 531 - 536
[9] CATION DICYCLOPENTADIENYLDICARBONYLVANADIUM(III)
CALDERAZZO, F
BACCIARE.S
[J]. INORGANIC CHEMISTRY, 1963, 2 (04) : 721 - +
[10] CALDERAZZO F, UNPUB J ORGANOMET CH

← 1 2 3 4 →