The titanocene dicarbonyl dication [TiCp2(CO)(2)](2+)

被引：11

作者：

Calderazzo, F ^{[1
]}

Pampaloni, G ^{[1
]}

Tripepi, G ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 23期

关键词：

D O I：

10.1021/om970634n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two-electron oxidation of TiCp2(CO)(2) or double protonation of TiCp4 in toluene under carbon monoxide affords an exceedingly moisture-sensitive solid which has been isolated and identified as the tetraphenylborato derivative of the titanocene dicarbonyl dication [TiCp2(CO)(2)](2+) on the basis of both spectroscopic data and reactivity.

引用

页码：4943 / 4944

页数：2

共 39 条

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