The outside knows the difference inside: trapping helium by immediate reduction of the orifice size of an open-cage fullerene and the effect of encapsulated helium and hydrogen upon the NMR of a proton directly attached to the outside

被引:33
作者
Chuang, Shih-Ching
Murata, Yasujiro [1 ]
Murata, Michihisa
Komatsu, Koichi
机构
[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
[2] Fukui Univ Technol, Dept Environm & Biotechnol Frontier Engn, Fukui 9108505, Japan
关键词
D O I
10.1039/b702589k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A methodology to entrap He inside an open-cage fullerene by immediate reduction of the size of an orifice was developed, and the effects of encapsulated He and H-2 on the chemical shift of a proton directly attached to the outer fullerene sphere were revealed.
引用
收藏
页码:1751 / 1753
页数:3
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