Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen

被引：29

作者：

Chuang, Shih-Ching

Murata, Yasujiro ^{[1
]}

Murata, Michihisa

Mori, Sadayuki

Maeda, Shuhei

Tanabe, Fumiyuki

Komatsu, Koichi

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Fukui Univ Technol, Dept Environm & Biotechnol Frontier Engn, Fukui 9108505, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 12期

关键词：

D O I：

10.1039/b616478a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

引用

页码：1278 / 1280

页数：3

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