New TTF derivatives with pyridine groups: synthesis, electrochemical studies, crystal structure and formation of conducting LB films

被引:35
作者
Jia, CY [1 ]
Zhang, DQ [1 ]
Xu, Y [1 ]
Xu, W [1 ]
Hu, HM [1 ]
Zhu, DB [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Ctr Mol Sci, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
electron donor; TTF; pyridine; conducting LB films;
D O I
10.1016/S0379-6779(02)00458-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electron donors with two and four pyridine groups 1-6 were synthesized and characterized. Their oxidation potentials were determined with cyclic voltammetry. A 3D supramolecular complex was formed between 3 and chloranilic acid (CA), and the crystal structure of this neutral complex was determined. Conducting LB films with room temperature conductivity Up to 1.1 x 10(-3) S cm(-1) were prepared from electron donors 1 and 4. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:249 / 255
页数:7
相关论文
共 18 条
[1]  
Andreu R, 2000, EUR J ORG CHEM, V2000, P737, DOI 10.1002/(SICI)1099-0690(200003)2000:5<737::AID-EJOC737>3.0.CO
[2]  
2-6
[3]   Semiconducting Langmuir-Blodgett films of ethylenedithiotetrathiafulvalene (EDT-TTF) derivatives bearing charged and uncharged aromatic substituents [J].
Goldenberg, LM ;
Becker, JY ;
Levi, OPT ;
Khodorkovsky, VY ;
Shapiro, LM ;
Bryce, MR ;
Cresswell, JP ;
Petty, MC .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (06) :901-907
[4]   SEMICONDUCTING LANGMUIR-BLODGETT-FILMS OF NON-AMPHIPHILIC ETHYLENEDITHIO-TETRATHIAFULVALENE DERIVATIVES BEARING PYRIDINE AND PYRIDINIUM SUBSTITUENTS [J].
GOLDENBERG, LM ;
BECKER, JY ;
LEVI, OPT ;
KHODORKOVSKY, VY ;
BRYCE, MR ;
PETTY, MC .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (04) :475-476
[5]   STRUCTURE OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM TRIBROMODICUPRATE(I), (BEDT-TTF+)CUI2BR3 - COORDINATION OF THE ORGANIC RADICAL CATION TO THE METAL-IONS [J].
INOUE, MB ;
INOUE, M ;
BRUCK, MA ;
FERNANDO, Q .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (06) :515-516
[6]   CuII coordination complex involving TTF-py as ligand [J].
Iwahori, F ;
Golhen, S ;
Ouahab, L ;
Carlier, R ;
Sutter, JP .
INORGANIC CHEMISTRY, 2001, 40 (26) :6541-+
[7]   A new approach to 4-alkylthio-1,3-dithiole-2-thione: An unusual reaction of a zinc complex of 1,3-dithole-2-thione-4,5-dithiolate [J].
Jia, CY ;
Zhang, DQ ;
Xu, W ;
Zhu, DB .
ORGANIC LETTERS, 2001, 3 (12) :1941-1944
[8]   Langmuir-Blodgett films of BEDT-TTF derivatives containing hydroxyl groups with long alkyl chains [J].
Li, HX ;
Zhang, DQ ;
Xu, Y ;
Xu, W ;
Yu, G ;
Li, XG ;
Zhu, DB .
SYNTHETIC METALS, 2001, 123 (03) :385-389
[9]   CONDUCTIVE AND OPTICALLY NON-LINEAR POLYMERIC LANGMUIR-BLODGETT FILMS OF POLY(3-DODECYLTHIOPHENE) [J].
LOGSDON, PB ;
PFLEGER, J ;
PRASAD, PN .
SYNTHETIC METALS, 1988, 26 (04) :369-381
[10]  
Moore AJ, 2001, EUR J ORG CHEM, V2001, P73, DOI 10.1002/1099-0690(200101)2001:1<73::AID-EJOC73>3.0.CO