The concept of the 'reaction cavity': A link between solution and solid-state chemistry

被引：48

作者：

Boldyreva, EV ^{[1
]}

机构：

[1] RAS, SD, Inst Solid State Chem, Novosibirsk 630128, Russia

来源：

SOLID STATE IONICS | 1997年 / 101卷

关键词：

reaction cavity; effects of the environment; organic solid-state chemistry; inorganic solid-state chemistry; solution chemistry; mechanical stresses;

D O I：

10.1016/S0167-2738(97)00318-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemical behaviour of molecules in a condensed state is known to be sensitive to their environment. The present contribution reviews the main approaches to this problem in the chemistry of solutions, as well as in the chemistry of inorganic and organic solids. The development of the concept of the 'reaction cavity' and the importance of this concept for the theory of solid-state reactivity and for practical applications of solid-state chemistry are discussed.

引用

页码：843 / 849

页数：7

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