Nitrogen atom transfer to alkenes utilizing chloramine-T as a nitrogen source

被引:123
作者
Ando, T [1 ]
Minakata, S [1 ]
Ryu, I [1 ]
Komatsu, M [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 565, Japan
关键词
D O I
10.1016/S0040-4039(97)10553-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Aziridination of alkenes proceeds successfully using Chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide). When anhydrous Chloramine-T was added to an acetonitrile solution of alkenes in the presence of various CuCl catalysts and MS-5A, the corresponding aziridines were obtained in moderate to good yields. (C) 1997 Elsevier Science Ltd. All rights reserved.
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页码:309 / 312
页数:4
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