Solution deposited NiO thin-films as hole transport layers in organic photovoltaics

被引:280
作者
Steirer, K. Xerxes [1 ,2 ]
Chesin, Jordan P. [3 ]
Widjonarko, N. Edwin [2 ,4 ]
Berry, Joseph J. [2 ]
Miedaner, Alex [2 ]
Ginley, David S. [2 ]
Olson, Dana C. [2 ]
机构
[1] Colorado Sch Mines, Dept Appl Phys, Golden, CO 80401 USA
[2] Natl Renewable Energy Lab, Natl Ctr Photovolta, Golden, CO 80401 USA
[3] Brown Univ, Div Engn, Providence, RI 02912 USA
[4] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
关键词
Hole transport layer; Nickel oxide; NiO; Organic solar cells; Anode surface modifier; PEDOT:PSS; SOLAR-CELLS; INTERFACE; OXIDE;
D O I
10.1016/j.orgel.2010.05.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Organic solar cells require suitable anode surface modifiers in order to selectively collect positive charge carriers and improve device performance. We employ a nickel metal organic ink precursor to fabricate NiO hole transport layers on indium tin oxide anodes. This solution deposited NiO annealed at 250 degrees C and plasma treated, achieves similar OPV device results reported with NiO films from PLD as well as PEDOT:PSS. We demonstrate a tunable work function by post-processing the NiO with an O-2-plasma surface treatment of varied power and time. We find that plasma treatment is necessary for optimal device performance. Optimal devices utilizing a solution deposited NiO hole transport layer show lower series resistance and increased fill factor when compared to solar cells with PEDOT: PSS. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1414 / 1418
页数:5
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