Chiral catalysts confined in porous hosts. 1. Synthesis

被引：37

作者：

Hultman, HM ^{[1
]}

de Lang, M ^{[1
]}

Nowotny, M ^{[1
]}

Arends, IWCE ^{[1
]}

Hanefeld, U ^{[1
]}

Sheldon, RA ^{[1
]}

Maschmeyer, T ^{[1
]}

机构：

[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands

来源：

JOURNAL OF CATALYSIS | 2003年 / 217卷 / 02期

关键词：

dirhodium catalyst; immobilisation; MCM-41; silica; SELECTIVITY;

D O I：

10.1016/S0021-9517(02)00154-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chiral dirhodium carboxamide catalysts were immobilised inside the pores of MCM-41 and on a low-surface-area silica (Aerosil 200). The catalysts were immobilised via ligand exchange of one chiral ligand with a carboxylate tether group. In part 2 the catalytic activity of these catalysts is reported. (C) 2003 Elsevier Science (USA). All rights reserved.

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页码：264 / 274

页数：11

相关论文

共 23 条

[1] Chiral catalysis on solids [J].

Baiker, A .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1998, 3 (01) :86-93

[2] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[3] Asymmetric catalysis on solids [J].

Bein, T .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1999, 4 (01) :85-96

[4] CATALYSTS AND BIOCATALYSTS ANCHORED TO INORGANIC SUPPORTS [J].

CAPKA, M .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1990, 55 (12) :2803-2839

[5] From microporous to mesoporous molecular sieve materials and their use in catalysis [J].

Corma, A .

CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419

[6] DIRHODIUM(II) TETRAKIS(CARBOXAMIDATES) WITH CHIRAL LIGANDS - STRUCTURE AND SELECTIVITY IN CATALYTIC METAL CARBENE TRANSFORMATIONS [J].

DOYLE, MP ;

WINCHESTER, WR ;

HOORN, JAA ;

LYNCH, V ;

SIMONSEN, SH ;

GHOSH, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :9968-9978

[7]

Fodor K, 1999, ENANTIOMER, V4, P497

[8] REACTIVITY OF A TRIMETHYLSTANNYL MOLYBDENUM COMPLEX IN MESOPOROUS MCM-41 [J].

HUBER, C ;

MOLLER, K ;

BEIN, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) :2619-2620

[9]

HULTMAN HM, IN PRESS J CATAL

[10] Superior performance of a chiral catalyst confined within mesoporous silica [J].

Johnson, BFG ;

Raynor, SA ;

Shephard, DS ;

Mashmeyer, T ;

Thomas, JM ;

Sankar, G ;

Bromley, S ;

Oldroyd, R ;

Gladden, L ;

Mantle, MD .

CHEMICAL COMMUNICATIONS, 1999, (13) :1167-1168